基于光谱分析的CO_2激光+脉冲GMAW复合焊峰值状态激光能量传输研究

在激光+脉冲GMAW复合焊接过程中,焊丝端部金属熔化产生大量的金属蒸汽,导致等离子体中电子、粒子的扩散现象加剧,使得激光的传输模式和工件对激光能量的吸收率和吸收模式发生变化。基于光谱分析的方法得到了复合焊接峰值状态的电子密度和温度分布,通过高速摄影分析了不同焊接模式下等离子体形态的变化,结合Beer-Lambert吸收定律计算了不同焊接模式下激光的吸收率。结果表明,在复合焊过程中,由于焊丝端部金属被熔化,焊丝的金属蒸汽进入激光等离子体内部,导致激光匙孔上方电子密度进一步提高,等离子体吸收激光能量能力增强,使得激光的传输效率从纯激光焊的94.16%降低到了CO_2激光+脉冲GMAW复合焊的85.84%。     

New 3D and 2D supramolecular heteroleptic palladium(II) dithiocarbamates as potent anticancer agents

Three new heteroleptic palladium(II) dithiocarbamates with better in vitro anticancer activity than cisplatin were synthesized and characterized by different analytical techniques, elemental analysis, FTIR, NMR, and single crystal X-ray diffraction analysis. The Pd center is chelated by dithiocarbamate ligand {4-benzylpiperazine-1-carbodithioate (1) and (3) or (4-(2-methoxyphenyl)piperazine-1-carbodithioate (2)}, triorganophosphine {tris-(4-flourophenyl)-phosphine (1) and (2) or tris-(4-chlorophenyl)phosphine (3)}, and a chloro-group, resulting in a square planar geometry. The packing diagram reveals a 3D network (1 and 2) and a 2D network (3) composed of various 1D chains in which the molecules are linked via hydrogen bonds (1–3) and halide?π (1, 3) interactions. The anticancer activities of complexes against HeLa cell line varies in the sequence 2 (23.438 μM) > 1 (38.293 μM) > 3 (47.554 μM) > cisplatin (78.075 μM). The cytotoxicity of these complexes is due to their strong induction of oxidative stress and DNA-damage ability leading to apoptosis.     

The influence of sub-Tg annealing on environmental stress cracking resistance of polycarbonate

To explore the effect of physical aging on environmental stress cracking (ESC) behavior of polycarbonate (PC), sub-T_g annealing was utilized as a method for accelerated aging. Injection molded samples were annealed at 130 °C for different time varying up to 96 h. A three point bending apparatus was used to evaluate critical stress for crazing and to record the variation of stress with immersion time at constant strain. The ESC results indicated that the critical stress for crazing initiation of PC in ethanol is increased by sub-T_g annealing. However, the resistance of annealed PC to ESC with immersion time during the stress relaxation test depends on the level of initial stress. When a relatively low initial stress was used, a short time (24 h) of sub-T_g annealing reduced the stress relaxation rate and decreased the number of cracks on the surface of PC. However, under higher initial stress, the stress relaxation rate of PC had a slight change only when the annealing time was prolonged about threefold (72 h). This can be explained by the formation of cohesional entanglement sites during the sub-T_g annealing process, which was demonstrated by the thermal and dynamic mechanical tests.     

基于合成规则的相似性推理及其在焊接参数设计中的应用

焊接过程是典型的复杂过程,应用模糊逻辑建立焊接参数推理系统可快速实现焊接工艺参数设计.近似推理机制是模糊系统研究和开发中的一个重要组成部分,在现有的相似性推理方法的基础上,融合经典的合成规则推理技术,提出一种新的基于合成规则的相似性推理方法.以CO_2保护焊焊接规范参数设计为背景介绍模糊推理在焊接领域的应用,运行结果表明,采用方法建立的模糊推理模型具有较高的推算精度,能够满足焊接工艺参数设计的要求.     

基于滑动Kriging插值的MLPG法求解结构非耦合热应力问题

将基于滑动Kriging插值的无网格局部Petrov-Galerkin(MLPG)法用来求解二维结构非耦合热应力问题,首先进行瞬态热传导的求解,然后再通过顺序耦合法将不同时刻节点温度作为附加体力项施加到应力分析中.瞬态温度场和非耦合热应力分析通过加权余量法来离散,同时用Heaviside分段函数作为局部弱形式的权函数.由于滑动Kriging插值构造的形函数满足Kroneckerδ函数的性质,因此方便了本质边界条件的施加.刚度矩阵形成过程中只涉及到边界积分而没有涉及到区域积分,因此可以减少计算工作量,最后通过两个数值算例来验证本文方法的有效性.     

完备流形上拉普拉斯算子的L2特征形式

本文研究了完备非紧流行上拉普拉斯算子的L²特征形式.利用应力能量张量的方法,得到在此类流形上拉普拉斯算子的L²特征形式的一些不存在性定理。     

尼龙1010应力松弛行为研究

尼龙1010样品在初始应变为1%、2.8%和5.1%的条件下,在不同的恒温环境中分别进行不少于10 h的应力松弛实验,得到20~80℃范围的应力松弛曲线.研究了不同应力、温度下的应力松弛速率、松弛过程的残余应力、活化体积以及相关参数的数学关系.结果表明,尼龙样品在松弛过程中存在一定的形变残余应力,体系存在恒定的长时模量.不同初始应变的尼龙样品松弛过程表现出相似的规律,当松弛速率-d(σ/σ0)/dlnt达到最大值后,在一段时间内聚合物内部活化单元发生松弛,-dσ/dt与作用于样品的有效应力σ*为指数关系.随着松弛过程的进行,应力减小到一定程度后,活化体积V逐渐增加,此时独立的活化单元运动受到限制,聚合物内部依靠多个活化单元的协同运动将内应力逐渐松弛,应力辅助功Vσ*为常数,-dσ/dt与σ*满足幂律关系,幂指数为σ*V/(k T).     

Chemical composition and insecticidal activities of essential oils against diamondback moth,Plutella xylostella (L.) (Lepidoptera: Yponomeutidae)

Five Himalayan plants namely, Acorus calamus, Cedrus deodara, Aegle marmelos, Tagetes minuta and Murraya koenigii were used for the extraction of essential oils through hydrodistillation and the major volatile constituents as identified by GC and GC–MS techniques were β-asarone (91.1%), β-himachalene (45.8%), limonene (59.5%), Z-ocimene (37.9%) and α-pinene (54.2%), respectively. Essential oils were tested for their insecticidal properties against larvae of diamondback moth, Plutella xylostella (L.) (Lepidoptera: Yponomeutidae). Results showed that A. calamus was most toxic (LC_50?=?0.29 mg mL^?1) to P. xylostella followed by C. deodara (LC_50?=?1.08 mg mL^?1) and M. koenigii (LC_50?=?1.93 mg mL^?1) via residual toxicity bioassay. Per cent feeding deterrence index and growth inhibition was significantly higher in A. calamus (42.20 and 68.55, respectively) followed by C. deodara (35.41 and 52.47). In repellent activity studies, C. deodara showed high repellence (64.76%) followed by A. calamus (55.05%).     

Convergence of goal‐oriented adaptive finite element methods for nonsymmetric problems

In this article, we develop convergence theory for a class of goal‐oriented adaptive finite element algorithms for second‐order nonsymmetric linear elliptic equations. In particular, we establish contraction results for a method of this type for Dirichlet problems involving the elliptic operator with A Lipschitz, symmetric positive definite, with b divergence‐free, and with . We first describe the problem class and review some standard facts concerning conforming finite element discretization and error‐estimate‐driven adaptive finite element methods (AFEM). We then describe a goal‐oriented variation of standard AFEM. Following the recent work of Mommer and Stevenson for symmetric problems, we establish contraction and convergence of the goal‐oriented method in the sense of the goal function. Our analysis approach is signficantly different from that of Mommer and Stevenson, combining the recent contraction frameworks developed by Cascon, Kreuzer, Nochetto, and Siebert; by Nochetto, Siebert, and Veeser; and by Holst, Tsogtgerel, and Zhu. We include numerical results, demonstrating performance of our method with standard goal‐oriented strategies on a convection problem. © 2015 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 32: 479–509, 2016